A PROTON EXCHANGE MEMBRANE PREPARED BY RADIATION GRAFTING OF p-STYRYLTRIMETHOXYSILANE INTO PTFE MEMBRANE
نویسندگان
چکیده
منابع مشابه
Dynamic investigation of hydrocarbon proton exchange membrane Fuel Cell
Sulfonated polyether ether ketone (SPEEK) is categorized in a nonfluorinated aromatic hydrocarbon proton exchange membrane (PEM) group and considered as a suitable substitute for common per-fluorinated membranes, such as Nafion, due to wider operating temperature, less feed gas crossover, and lower cost. Since modeling results in a better understanding of a phenomenon, in this study a dynamic o...
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Heterogeneous proton exchange membranes (PEM) are synthesized using the dry phase inversion technique. The casting solutions are prepared by dispersing a finely ground cation exchange resin particle in N,N-dimethylacetamide (DMAc) solution of polyvinyl-chloride (PVC). Results show that ion exchange capacity is increased with the addition of 1 %-wt nanosilica (from 0.14 to 0.27 meq/g) while it i...
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An essential requirement for an operating PEM fuel cell is providing proper water content in the membrane. To avoid water flooding an appropriate water balance is required. Here, an analytic model of a planar membrane humidifier for PEM fuel cell is proposed where the effect of dimensional parameters includes membrane thickness, membrane area and channel hydraulic diameter are investigated. A N...
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Sulfonated poly (ether ether ketone) (SPEEK) with a low degree of sulfonation (DS = 40%) was prepared for proton exchange membrane fuel cells (PEMFC). Poly (ether ether ketone) (PEEK) was sulfonated in concentrated H2SO4 under N2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (H-NMR) technique. After preparation of the SPEEK polymer, the obtained polymer was dissolved i...
متن کاملModified CNTs/Nafion composite: The role of sulfonate groups on the performance of prepared proton exchange methanol fuel cell’s membrane
A novel Nafion®-based nanocomposite membrane was synthesized to be applied as direct methanol fuel cells (DMFCs). Carbon nanotubes (CNTs) were coated with a layer of silica and then reacted by chlorosulfonic acid to produce sulfonate-functionalized silicon dioxide coated carbon nanotubes (CNT@SiO2-SO3H). The functionalized CNTs were then introduced to Nafion®, and subsequently, methanol permeab...
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ژورنال
عنوان ژورنال: Acta Polymerica Sinica
سال: 2010
ISSN: 1000-3304
DOI: 10.3724/sp.j.1105.2010.09258